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1.14.14.37: 4-hydroxyphenylacetaldehyde oxime monooxygenase

This is an abbreviated version!
For detailed information about 4-hydroxyphenylacetaldehyde oxime monooxygenase, go to the full flat file.

Word Map on EC 1.14.14.37

Reaction

(E)-4-hydroxyphenylacetaldehyde oxime
+
[reduced NADPH-hemoprotein reductase]
+
O2
=
(S)-4-hydroxymandelonitrile
+
[oxidized NADPH-hemoprotein reductase]
+ 2 H2O

Synonyms

4-hydroxybenzeneacetaldehyde oxime monooxygenase, 4-hydroxyphenylacetaldehyde oxime monooxygenase, CYP71E, CYP71E1, cytochrome P450II-dependent monooxygenase, EC 1.14.13.42, EC 1.14.13.68, NADPH-cytochrome P450 reductase

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.14.37 4-hydroxyphenylacetaldehyde oxime monooxygenase

Systematic Name

Systematic Name on EC 1.14.14.37 - 4-hydroxyphenylacetaldehyde oxime monooxygenase

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SYSTEMATIC NAME
IUBMB Comments
(E)-4-hydroxyphenylacetaldehyde oxime,[reduced NADPH—hemoprotein reductase]:oxygen oxidoreductase
This cytochrome P-450 (heme thiolate) enzyme is involved in the biosynthesis of the cyanogenic glucoside dhurrin in sorghum. It catalyses three different activities - isomerization of the (E) isomer to the (Z) isomer, dehydration, and C-hydroxylation.