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1.14.14.37: 4-hydroxyphenylacetaldehyde oxime monooxygenase

This is an abbreviated version!
For detailed information about 4-hydroxyphenylacetaldehyde oxime monooxygenase, go to the full flat file.

Word Map on EC 1.14.14.37

Reaction

(E)-4-hydroxyphenylacetaldehyde oxime
+
[reduced NADPH-hemoprotein reductase]
+
O2
=
(S)-4-hydroxymandelonitrile
+
[oxidized NADPH-hemoprotein reductase]
+ 2 H2O

Synonyms

4-hydroxybenzeneacetaldehyde oxime monooxygenase, 4-hydroxyphenylacetaldehyde oxime monooxygenase, CYP71E, CYP71E1, cytochrome P450II-dependent monooxygenase, EC 1.14.13.42, EC 1.14.13.68, NADPH-cytochrome P450 reductase

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.14.37 4-hydroxyphenylacetaldehyde oxime monooxygenase

Reaction

Reaction on EC 1.14.14.37 - 4-hydroxyphenylacetaldehyde oxime monooxygenase

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REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(E)-4-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 = (S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
overall reaction
-
-
-
(E)-4-hydroxyphenylacetaldehyde oxime = (Z)-4-hydroxyphenylacetaldehyde oxime
show the reaction diagram
(1a)
-
-
-
(Z)-4-hydroxyphenylacetaldehyde oxime = 4-hydroxyphenylacetonitrile + H2O
show the reaction diagram
(1b)
-
-
-
4-hydroxyphenylacetonitrile + [reduced NADPH-hemoprotein reductase] + O2 = (S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
(1c)
-
-
-