1.14.13.92: phenylacetone monooxygenase
This is an abbreviated version!
For detailed information about phenylacetone monooxygenase, go to the full flat file.
Word Map on EC 1.14.13.92
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1.14.13.92
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baeyer-villiger
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ketone
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enantioselectivity
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bvmos
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thermobifida
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biocatalytic
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cyclohexanone
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fusca
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synthesis
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sulfoxidations
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biocatalyst
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phosphite
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cyclopentanone
- 1.14.13.92
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baeyer-villiger
- ketone
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enantioselectivity
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bvmos
-
thermobifida
-
biocatalytic
- cyclohexanone
- fusca
- synthesis
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sulfoxidations
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biocatalyst
- phosphite
- cyclopentanone
Reaction
Synonyms
4-hydroxyacetophenone monooxygenase, Baeyer-Villiger monooxygenase, BVMO, EtaA, HAPMO, M-PAMO, More, PAMO, phenylacetone monooxygenase, Tf PAMO
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Natural Substrates Products
Natural Substrates Products on EC 1.14.13.92 - phenylacetone monooxygenase
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REACTION DIAGRAM
benzyl acetate + NADP+ + H2O
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phenylacetone + NADPH + H+ + O2
benzyl acetate + NADP+ + H2O
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phenylacetone + NADPH + H+ + O2
benzyl acetate + NADP+ + H2O
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phenylacetone + NADPH + H+ + O2
benzyl acetate + NADP+ + H2O
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substrate specificity and reaction mechanism, the enzyme shows high specificity towards short-chain aliphatic ketones, some open-chain ketones are converted to the alkylacetates, while for others formation of the ester products with oxygen on the other side of the keto group can also be detected yielding the corresponding methyl or ethyl esters, overview
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additional information
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substrate specificity and reaction mechanism, the enzyme shows high specificity towards short-chain aliphatic ketones, some open-chain ketones are converted to the alkylacetates, while for others formation of the ester products with oxygen on the other side of the keto group can also be detected yielding the corresponding methyl or ethyl esters, overview
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