1.14.13.226: acetone monooxygenase (methyl acetate-forming)

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For detailed information about acetone monooxygenase (methyl acetate-forming), go to the full flat file.

Reaction

Synonyms

AcmA

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor

                1.14.13.226 acetone monooxygenase (methyl acetate-forming)

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1	AA Sequence
2	Cofactor
2	Molecular Weight [Da]
1	Natural Substrates/ Products (Substrates)
1	Organism
3	Pathway
1	pH Optimum
1	Purification (Commentary)
1	Reaction
1	Reference
10	Substrates and Products (Substrate)
1	Subunits
1	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]

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Substrates Products on EC 1.14.13.226 - acetone monooxygenase (methyl acetate-forming)

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

acetone + NADPH + H+ + O2

methyl acetate + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

-

738519

enzyme catalyzes stoichiometric conversion of acetone to methyl acetate with consumption of NADPH

-

?

butan-2-one + NADPH + H+ + O2

methyl propanoate + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

82% of the activity with acetone

738519

-

-

?

cyclobutanone + NADPH + H+ + O2

? + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

131% of the activity with acetone

738519

-

-

?

cyclohexanone + NADPH + H+ + O2

? + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

135% of the activity with acetone

738519

-

-

?

cyclopentanone + NADPH + H+ + O2

? + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

170% of the activity with acetone

738519

-

-

?

decan-2-one + NADPH + H+ + O2

methyl nonanoate + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

173% of the activity with acetone

738519

-

-

?

heptan-2-one + NADPH + H+ + O2

methyl hexanoate + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

80.7% of the activity with acetone

738519

-

-

?

nonan-2-one + NADPH + H+ + O2

methyl octanoate + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

186% of the activity with acetone

738519

-

-

?

octan-2-one + NADPH + H+ + O2

methyl heptanoate + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

128% of the activity with acetone

738519

-

-

?

pentan-2-one + NADPH + H+ + O2

methyl butanoate + NADP+ + H2O

Gordonia sp. TY-5

A1IHE6

45% of the activity with acetone

738519

-

-

?