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1.14.13.22: cyclohexanone monooxygenase

This is an abbreviated version!
For detailed information about cyclohexanone monooxygenase, go to the full flat file.

Word Map on EC 1.14.13.22

Reaction

cyclohexanone
+
NADPH
+
H+
+
O2
=
hexano-6-lactone
+
NADP+
+
H2O

Synonyms

Bpro_556, CAMO, CHMO, ChnB, chnB protein, chnB1 protein, CHXON, CMO, cycloalkaone monooxygenase, cyclohexanone 1, 2-mono-oxygenase, cyclohexanone mono-oxygenase, cyclohexanone monooxygenase, cyclohexanone oxygenase, cyclohexanone:NADPH:oxygen oxidoreductase (lactone-forming), oxygenase, cyclohexanone mono-

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.13.22 cyclohexanone monooxygenase

KCat KM Value

KCat KM Value on EC 1.14.13.22 - cyclohexanone monooxygenase

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kcat/KM VALUE [1/mMs-1]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
1
2-butanone
pH 7.0, 25°C
38
2-hydroxycyclobutanone
pH 8.0, 25°C
2.3
2-phenylcyclohexanone
pH 8.0, 25°C
0.02 - 0.03
acetophenone
920
Cyclobutanone
pH 8.0, 25°C
4.9
Cycloheptanone
pH 8.0, 25°C
0.15 - 3150
cyclohexanone
0.7
Cyclooctanone
pH 8.0, 25°C
1.3 - 100
Cyclopentanone
3.16 - 1154
NADPH
0.28 - 5.79
O2
0.3 - 5
phenylacetone
12.5 - 43.4
pyrmetazole
-
3
thioanisole
-
pH 7.0, 25°C