1.14.13.187: L-evernosamine nitrososynthase
This is an abbreviated version!
For detailed information about L-evernosamine nitrososynthase, go to the full flat file.
Word Map on EC 1.14.13.187
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1.14.13.187
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thymidine
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monooxygenase
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micromonospora
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anthracycline
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flavin-dependent
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africana
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peucetius
- 1.14.13.187
- thymidine
- monooxygenase
- micromonospora
-
anthracycline
-
flavin-dependent
- africana
- peucetius
Reaction
+ 2 NADPH + 2 H+ + 2 O2 = + 2 NADP+ + 3 H2O
Synonyms
DnmZ, nitrososynthase, ORF36
ECTree
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Systematic Name
Systematic Name on EC 1.14.13.187 - L-evernosamine nitrososynthase
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dTDP-beta-L-evernosamine,NADPH:oxygen oxidoreductase (N-hydroxylating)
Requires FAD. Isolated from the bacterium Micromonospora carbonacea var. africana. The nitroso group is probably spontaneously oxidized to a nitro group giving dTDP-beta-L-evernitrose, which is involved in the biosynthesis of the antibiotic everninomycin. The reaction was studied using dTDP-beta-L-4-epi-vancosamine (dTDP-4-O-desmethyl-beta-L-evernitrosamine).