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1.1.3.47: 5-(hydroxymethyl)furfural oxidase

This is an abbreviated version!
For detailed information about 5-(hydroxymethyl)furfural oxidase, go to the full flat file.

Word Map on EC 1.1.3.47

Reaction

5-(dihydroxymethyl)furan-2-carbaldehyde
+
O2
=
5-formylfuran-2-carboxylate
+
H2O2

Synonyms

5-hydroxymethylfurfural oxidase, AAO, AOX1, GaoB, Glox2, Glox3, GLRG_02805, HFMO, HMF oxidase, HMF/furfural oxidoreductase, HmfH, HMFO, MPQ_0130

ECTree

     1 Oxidoreductases
         1.1 Acting on the CH-OH group of donors
             1.1.3 With oxygen as acceptor
                1.1.3.47 5-(hydroxymethyl)furfural oxidase

Substrates Products

Substrates Products on EC 1.1.3.47 - 5-(hydroxymethyl)furfural oxidase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(2R,3E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-ol + O2
(3E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-one + H2O2
show the reaction diagram
4% conversion, 2% enantiomeric excess
-
-
?
(2R,3E)-4-(4-chlorophenyl)but-3-en-2-ol + O2
(3E)-4-(4-chlorophenyl)but-3-en-2-one + H2O2
show the reaction diagram
10% conversion, 10% enantiomeric excess
-
-
?
(2R,3E)-4-(4-methylphenyl)but-3-en-2-ol + O2
(3E)-4-(4-methylphenyl)but-3-en-2-one + H2O2
show the reaction diagram
13% conversion, 14% enantiomeric excess
-
-
?
(2R,3E)-4-phenylbut-3-en-2-ol + O2
(3E)-4-phenylbut-3-en-2-one + H2O2
show the reaction diagram
29% conversion, 25% enantiomeric excess
-
-
?
(2R,3E)-oct-3-en-2-ol + O2
(3E)-oct-3-en-2-one + H2O2
show the reaction diagram
16% conversion, 19% enantiomeric excess
-
-
?
(R)-1-phenylethanol + O2
acetophenone + H2O2
show the reaction diagram
-
-
-
?
(S)-1-phenylethanol + O2
acetophenone + H2O2
show the reaction diagram
-
-
-
?
1-(4-chlorophenyl)ethanethiol + O2
1-(4-chlorophenyl)ethane-1-thione + (R)-1-(4-chlorophenyl)ethanethiol
show the reaction diagram
-
-
-
?
1-(4-fluorophenyl)ethanethiol + O2
1-(4-fluorophenyl)ethane-1-thione + (R)-1-(4-fluorophenyl)ethanethiol
show the reaction diagram
-
-
-
?
1-(4-methylphenyl)ethanethiol + O2
1-(4-methylphenyl)ethane-1-thione + (R)-1-(4-methylphenyl)ethanethiol
show the reaction diagram
-
-
-
?
1-phenylethanethiol + O2
1-phenylethane-1-thione + (R)-1-phenylethanethiol
show the reaction diagram
-
-
-
?
2,5-diformylfuran + 2 O2
2,5-furandicarboxylic acid + H2O2
show the reaction diagram
2,5-diformylfuran + O2
5-formylfuran-2-carboxylic acid + ?
show the reaction diagram
2,5-diformylfuran + O2
formylfurancarboxylic acid + ?
show the reaction diagram
-
-
-
?
2,5-hydroxymethylfurancarboxylic acid + O2
2,5-furandicarboxylic acid + H2O2
show the reaction diagram
very low activity
-
-
?
3-methoxybenzyl alcohol + O2
3-methoxybenzaldehyde + H2O2
show the reaction diagram
4-(hydroxymethyl)benzaldehyde + O2 + H2O
?
show the reaction diagram
-
-
-
?
4-anisaldehyde + O2
4-anisic acid + H2O2
show the reaction diagram
-
-
-
?
4-hydroxy-3-methoxybenzyl alcohol + O2
4-hydroxy-3-methoxybenzaldehyde + H2O2
show the reaction diagram
-
-
-
?
4-methoxybenzyl alcohol + O2
4-methoxybenzaldehyde + H2O2
show the reaction diagram
4-methoxybenzyl alcohol + O2
4-methoxybenzyl aldehyde + H2O2
show the reaction diagram
-
-
-
?
5-(dihydroxymethyl)furan-2-carbaldehyde + O2
5-formylfuran-2-carboxylate + H2O2
show the reaction diagram
5-(dihydroxymethyl)furan-2-carboxylate + O2
furan-2,5-dicarboxylate + H2O2
show the reaction diagram
5-(hydroxymethyl)furan-2-carbaldehyde + O2
5-formylfuran-2-carboxylate + H2O2
show the reaction diagram
-
-
-
?
5-(hydroxymethyl)furan-2-carboxylic acid + O2
2,5-formylfurancarboxylic acid + H2O2
show the reaction diagram
-
-
-
?
5-(hydroxymethyl)furan-2-carboxylic acid + O2
2,5-furandicarboxylic acid + ?
show the reaction diagram
very low activity
-
-
?
5-(hydroxymethyl)furan-2-carboxylic acid + O2
furan-2,5-dicarboxylic acid + ?
show the reaction diagram
5-(hydroxymethyl)furan-2-carboxylic acid + O2
furan-2-carbaldehyde-5-carboxylate + H2O2
show the reaction diagram
-
-
-
?
5-(hydroxymethyl)furfural + 3 O2 + 2 H2O
furan-2,5-dicarboxylate + 3 H2O2
show the reaction diagram
5-(hydroxymethyl)furfural + O2
5-(hydroxymethyl)furan-2-carboxylic acid + H2O2
show the reaction diagram
-
-
-
?
5-(hydroxymethyl)furfural + O2
furan-2,5-dicarbaldehyde + H2O2
show the reaction diagram
5-formylfuran-2-carboxylate + H2O
5-(dihydroxymethyl)furan-2-carboxylate
show the reaction diagram
-
-
-
?
5-formylfuran-2-carboxylate + O2
furan-2,5-dicarboxylate + H2O2
show the reaction diagram
5-hydroxymethylfurfural + O2
2,5-diformylfuran + H2O2
show the reaction diagram
5-hydroxymethylfurfural + O2
2,5-furandicarboxylic acid + ?
show the reaction diagram
5-hydroxymethylfurfural + O2
5-(hydroxymethyl)furan-2-carboxylic acid + H2O2
show the reaction diagram
5-hydroxymethylfurfural + O2
5-hydroxymethylfuran-2-carboxylic acid + H2O2
show the reaction diagram
-
-
-
?
benzyl alcohol + O2
benzaldehyde + H2O2
show the reaction diagram
cinnamyl alcohol + O2
cinnamaldehyde + H2O2
show the reaction diagram
formylfurancarboxylic acid + O2
2,5-furandicarboxylic acid + H2O2
show the reaction diagram
-
-
-
?
furan-2,5-dicarbaldehyde + H2O
5-(dihydroxymethyl)furan-2-carbaldehyde
show the reaction diagram
-
-
-
?
furan-2,5-dicarbaldehyde + O2
5-formylfuran-2-carboxylate + H2O2
show the reaction diagram
furan-2,5-dicarbaldehyde + O2
furan-2-carbaldehyde-5-carboxylate + H2O2
show the reaction diagram
-
-
-
?
furan-2-carbaldehyde-5-carboxylate + O2
furan-2,5-dicarboxylate + H2O2
show the reaction diagram
-
-
-
?
terephthaldehyde + O2 + H2O
?
show the reaction diagram
-
-
-
?
vanillyl alcohol + O2
vanillin + H2O2
show the reaction diagram
veratryl alcohol + O2
veratryl aldehyde + H2O2
show the reaction diagram
additional information
?
-