1.1.1.364: dTDP-4-dehydro-6-deoxy-alpha-D-gulose 4-ketoreductase
This is an abbreviated version!
For detailed information about dTDP-4-dehydro-6-deoxy-alpha-D-gulose 4-ketoreductase, go to the full flat file.
Reaction
Synonyms
GerKI
ECTree
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Natural Substrates Products on EC 1.1.1.364 - dTDP-4-dehydro-6-deoxy-alpha-D-gulose 4-ketoreductase
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REACTION DIAGRAM
dTDP-4-dehydro-6-deoxy-alpha-D-gulopyranose + NADH + H+
dTDP-6-deoxy-alpha-D-allopyranose + NAD+
the enzyme forms an activated deoxy-alpha-D-allose, which is converted to mycinose after attachment to the aglycones of several macrolide antibiotics, including tylosin, chalcomycin, dihydrochalcomycin, and mycinamicin II
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