1.1.1.260: sulcatone reductase
This is an abbreviated version!
For detailed information about sulcatone reductase, go to the full flat file.
Reaction
ECTree
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Substrates Products
Substrates Products on EC 1.1.1.260 - sulcatone reductase
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REACTION DIAGRAM
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol, 80% sulcatol R(-) enantiomer after 24 h reaction time
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
enantiomeric selectivity substantially affected by pregrowth period and substrate concentration
sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol, 80% of sulcatol R enantiomer after 48 h reaction time
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
96% sulcatol R enantiomer after 17 h reaction time, sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
only sensitive to S enantiomer, inhibited by the R enantiomer, sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol, mixture of 65% S(+)- and 35% S(-)-sulcatol isomers
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
R(-)-sulcatol in high enantiomeric excess formed irrespective of pregrowth period and substrate concentration
sulcatol
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
sulcatol, S enantiomer formed
r
6-methylhept-5-en-2-one + NADH
6-methylhept-5-en-2-ol + NAD+
-
sulcatone
100% enantiomeric excess for S(+)-sulcatol, sulcatol, S enantiomer formed
r